Product ID:REOLUBE MP 280B
MSDS Date:10/20/1999
FSC:9150
NIIN:01-113-2047
MSDS Number: CKBZV

Emergency Phone: 800-949-5167

Info Phone: 765-497-6100

Cage: 2E394

Telephone: 765-497-6100/800-949-5167

Cage: 2E394

TER-BUTYLATED TRIPHENYL PHOSPHATES

CAS: 68937-40-6

TRIPHENYL PHOSPHATE

CAS: 115-86-6

RTECS: TC8400000

OSHA PEL 3 MG/M3

ACGIH TLV: 3 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: NOT EXPECTED TO BE A HAZARD IN
NORMAL INDUSTRIAL USE. SKIN: NOT EXPECTED TO BE A HAZARD IN NORMAL
INDUSTRIAL USE. INGESTION: NOT EXPECTED TO BE A HAZARD IN NORMAL
INDUSTRIAL USE. INHALATION: N OT EXPECTED TO BE A HAZARD IN NORMAL
INDUSTRIAL USE. CHRONIC: MAY CAUSE REPRODUCTIVE AND FERTILITY
EFFECTS BASED ON ANIMAL DATA. EPIDEMIOLOGY STUDIES COMPLETED IN
1977 AND 1985 OF CURRENT AND FORMER WORKERS AT THE PRODUCTION
FACILITY WERE KRONITEX, DURAD, NATURAL AND SYNTHETIC TRIARYL
PHOSPHATE ESTERS ARE MANUFACTURED HAVE NOT DEMOSTRATED ANY UNUSUAL
PATTERN OF MORTALITY OR DISEASE.
Explanation of Carcinogenicity:ACGIH: NO. OTHER: NO.
Effects of Overexposure:NO KNOWN SIGNS AND SYMPTOMS OF EXPOSURE.

First Aid:EYES: FLUSH WITH LARGE VOLUMES OF WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. SKIN: WASH WITH LARGE VOLUMES OF
SOAP AND WATER FOR AT LEAST 15 MINUTES. IF IRRITATION DEVELOPS, GET
MEDICAL AT TENTION. INGESTION: IF CONSCIOUS, GIVE PERSON 1 TO 2
GLASSES OF WATER. GET MEDICAL ATTENTION IMMEDIATELY. INHALALATION:
REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION. ANTIDOTES: NO
INFORMATION AVA ILABLE. "SEE OTHER INFORMATION"

Flash Point Method:PMCC
Flash Point:=243.3C, 470.F
Autoignition Temp:=538.C, 1000.4F
Lower Limits:NOT AVAILABL
Upper Limits:NOT AVAILABL
Extinguishing Media:WATER FOG, CARBON DIOXIDE (CO2), DRY CHEMICAL,
MULTIPURPOSE FOAM.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT SKIN AND EYE CONTACT IN FIRE
SITUATIONS.
Unusual Fire/Explosion Hazard:UNDER FIRE CONDITIONS, TOXIC AND
IRRITATING FUMES MAY BE EMITTED. SLIGHTLY COMBUSTIBLE. NO EXPLOSION
HAZARD.

Spill Release Procedures:ABSORB SPILLED MATERIAL ON COMMERCIAL OIL
ABSORBANT OR SAND. PLACE IN SUITABLE LABELED CONTAINER FOR
DISPOSAL. OUT OF STREAMS AND SEWERS. AVOID RELEASING TO THE
ENVIRONMENT.

Handling and Storage Precautions:HANDLING-USE APPROPRIATE PERSONAL
PROTECTION EQUIPMENT. AVOID EYE, SKIN & CLOTHING CONTACT. DO NOT
BREATHE MIST OR VAPOR. AVOID REPEATED & PROLONGED CONTACT. AVOID
THE GENERATION OF AEROSOLS FROM SPRA YING, POURING OR VIGOROUS
AGITATION WHENEVER POSSIBLE, PARTICULARLY IF PRODUCT IS HEATED.
Other Precautions:STORAGE-IF THE GENERATION OF AIRBORNE MATERIAL CANNOT
BE AVOIDED, EXHAUST VENTILATION &/OR PERSONALK PROTECTIVE EQUIPMENT
SHOULD BE USED. STORAGE-STORE IN A COOL, DRY, WELL-VENTILATED AREA
AWAY FROM I NCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED.
PROTECT CONTAINER AGAINST DAMAGE.

Respiratory Protection:WEAR A NIOSH/MSHA APPROVED ORGANIC CARTRIDGE
RESPIRATOR IF MISTING OR VAPOR OCCURS, OR THERE IS POTENTIAL FOR
AIRBORNE EXPOSURES TO EXCEED ESTABLISHED THRESHOLD VALUES. CONSULT
THE OSHA RESPIRATORY PR OTECTION INFORMATION LOCATED AT 29 CFR
1910.134 AND THE AMERICAN NATIONAL STANDARD INSTITUTE'S PRACTICES
OF RESPIRATORY PROTECTION Z88.2. " SEE OTHER INFO"
Ventilation:USE LOCAL VENTILATION TO KEEP LEVELS BELOW ESTABLISHED
THRESHOLD VALUES. USE MECHANICAL VENTILATION FOR GENERAL AREA
CONTROL.
Protective Gloves:BUTYL(HEAVY DUTY) OR POLYETHYLENE (LIGHT DUTY)
GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:VITRON FLUOROELASTOMER, NITRILE AND LATEX
GLOVES ARE SUITABLE FOR SHORT TERM SERVICE. WEAR AN APRON OR
IMPERVIOUS CLOTHING AND RUBBER BOOTS IF SPLASHING IS EXPECTED.
Work Hygienic Practices:WASH THOROUGHLYAFTER HANDLING. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
PRODUCT NAME: REOLUBE MP 280B. SYNONYMS: TRIARYL PHOSPHATE,
TERT-BUTYLATED; DURAD MP 280B; TERT-BUTYLATED TRIPHENYL PHOSPHATE.
PRODUCT USE: HIGH PERFORMANCE HYDRAULIC FLUID. CHEMICAL NAME:
TERT-BUTYLA TED TRIPHENYL PHS\OSPHATE. CHEMICAL FAMILY: ARYL
PHOSPHATE.

HCC:V6
Boiling Pt:B.P. Text:220C TO 270C @4MMHG
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:0.033 MMHG AT 150C
Vapor Density:NOT AVAILA
Spec Gravity:1.145-1.165 @ 20 DEG C
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR LIQUID. ODOR: NONE. COLOR: NONE
Percent Volatiles by Volume:NONE PROVIDE
Corrosion Rate:NONE PROVIDED BY MFR

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS OF HANDLING
AND USE.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCT THE
FOLLOWING OXIDES OF PHOSPHORUS: CARBON MONOXIDE AND CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF WASTE AT AN APPROVED CHEMICAL
DISPOSAL FACILITY IN COMPLIANCE WITH ALL CURRENT LOCAL,
STATE/PROVINCE, FEDERAL/CANADIAN LAWS & REGS. IF THE PRODUCT WAS
SUPPLIED IN A SINGLE USE CONTAINER, CA RE SHOULD BE TAKEN TO
DISPOSE OF IN A RESPONSIBLE MANNER & IN ACCORDANCE WITH APPLICABLE
REGULATIONS . LABEL PRECAUTIONS SHOULD FOLLOW CONTAINERS.

Toxicological Information:ACUTE: BASED ON A SIMILAR PRODUCT, THIS
PRODUCT HAS LOW ACUTE ORAL AND DERMAL TOXICITY AND IS NOT
IRRITATING TO THE EYES AND SKIN. NO EVIDENCE OF DELAYED
NEUROTOXICITY WAS OBSERVED IN RATS & HENS FOLL OWING ACUTE
EXPOSURE. CHRONIC: NO DATA AVAILABLE FOR THE PRODUCT. BASED ON A
SIMILAR PRODUCT, THIS PRODUCT IS NOT MUTAGENIC IN THE AMES TEST. A
REPRODUCTIVE STUDY WITH A BUTYLATED TRIPHENYL PHOSPHATE INDICATED
A SIGNFICANT DECLINE IN REPRODUCTION IN FEMALE RATS CHARACTERIZED
BY LOW MATING & FERTILITY INDICES, DECREASED NUMBER OF LITTERS &
ABNORMAL ESTROUS CYCLES. FERTILITY WAS ALSO DECREASED IN MA LE
RATS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA AVAILABLE FOR THE PRODUCT. INFO GIVEN HERE IS FOR A
SIMILAR PRODUCT. 96 HR LC50 (RAINBOW TROUT)= 3.4 (2.8-4.0) MG/L; 96
HR LC50(FATHEAD MINNOW)= 42.3(32.6-54.9) MG/L; 48 HR EC50 (DAPHNIA
MAGNA )=3.9 (3.2-4.7) MG/L. NO DATA AVAILABLE ON CHEMICAL FATE.

Transport Information:U.S. DOT. PROPER SIPPING NAME: ENVIRONMENTALLY
HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TRIPHENYL
PHOSPHATE/TER-BUTYLATED TRIPHENYL PHOSPHATE MIXTURES CONTAINING 10%
TO 48% TRIPHENYL PHOSPHATE). HAZARD CL ASS: 9. GROUP: III. SPECIAL
PROVISIONS: 8, N50, T1. NON-BULK PACKAGING: 203. PASSENGER AIR/RAIL
LIMIT: NONE. VESSEL STOWAGE: A. REPORTABLE QUANTITY: N/A. ID
NUMBER: UN3082. LABELS: MISCELLANEOUS, MARI NE POLLUTANT. PACKAGING
EXECPTIONS: 155. BULK PACKAGING: 241. AIR CARGO LIMIT: NONE. OTHER
STOWAGE: N/A.

SARA Title III Information:SARA HAZARDS: ACUTE-NO, REACTIVE-NO,
PRESSURE-NO, CHRONIC-YES, FIRE-NO.
Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT ARE
EITHER ON THE TSCA INVENTORY OR EXEMPT (I.E. IMPURITIES, A POLYMER
COMPLYING WITH THE EXEMPTION RULE AT 40 CFR 728.250) FROM THE
INVENTORY.
State Regulatory Information:STATE REGULATIONS: TRIPHENYL PHOSPHATE:
MASSACHUSETTES SUBSTANCE LIST, NEW JERSEY RIGHT TO KNOWN SUBSTANCE
LIST (1% REPORTING LIMIT), PENNSYLVANIA HAZARDOUS SUBSTANCE LIST
(1% REPORTING LIMIT).